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Misleading
mineral may have resulted in overestimate of water in moon
Misleading
mineral may have resulted in overestimate of water in moon
Date:
April 1,
2014
Source:
University of California - Los
Angeles
Summary:
The amount of water present in the moon may have been
overestimated by scientists studying the mineral apatite, researchers have
discovered. For decades, scientists believed the moon was almost entirely
devoid of water. However, the discovery of hydrogen-rich apatite within lunar
rocks in 2010 seemed to hint at a more watery past. Scientists originally
assumed that information obtained from a small sample of apatite could predict
the original water content of a large body of magma, or even the entire moon,
but a new study indicates that apatite may, in fact, be deceptive.
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The amount
of water present in the moon may have been overestimated by scientists studying
the mineral apatite, says a team of researchers led by Jeremy Boyce of the UCLA
Department of Earth, Planetary and Space Sciences.
Boyce and
his colleagues created a computer model to accurately predict how apatite would
have crystallized from cooling bodies of lunar magma early in the moon's
history. Their simulations revealed that the unusually hydrogen-rich apatite
crystals observed in many lunar rock samples may not have formed within a
water-rich environment, as was originally expected.
This
discovery has overturned the long-held assumption that the hydrogen in apatite
is a good indicator of overall lunar water content.
"The
mineral apatite is the most widely used method for estimating the amount of
water in lunar rocks, but it cannot be trusted," said Boyce, who is an
adjunct assistant professor in the UCLA College of Letters and Science.
"Our new results show that there is not as much water in lunar magma as apatite
would have us believe."
The research
was published online March 20 in the journal Science on and will be
published in a future print edition.
For decades,
scientists believed the moon was almost entirely devoid of water. However, the
discovery of hydrogen-rich apatite within lunar rocks in 2010 seemed to hint at
a more watery past. Scientists originally assumed that information obtained
from a small sample of apatite could predict the original water content of a
large body of magma, or even the entire moon, but Boyce's study indicates that
apatite may, in fact, be deceptive.
Boyce
believes the high water content within lunar apatite results from a quirk in
the crystallization process rather than a water-rich lunar environment. When
water is present as molten rock cools, apatite can form by incorporating
hydrogen atoms into its crystal structure. However, hydrogen will be included
in the newly crystallizing mineral only if apatite's preferred building blocks,
fluorine and chlorine, have been mostly exhausted.
"Early-forming
apatite is so fluorine-rich that it vacuums all the fluorine out of the magma,
followed by chlorine," Boyce said. "Apatite that forms later doesn't
see any fluorine or chlorine and becomes hydrogen-rich because it has no
choice."
Therefore,
when fluorine and chlorine become depleted, a cooling body of magma will shift
from forming hydrogen-poor apatite to forming hydrogen-rich apatite, with the
latter not accurately reflecting the original water content in the magma.
Understanding
the story of lunar apatite has implications beyond determining how much water
is locked inside lunar rocks and soil. According to the predominant theory of
how the moon originally formed, hydrogen and other volatile elements should not
be present at all in lunar rocks.
Many
scientists theorize that the moon formed when a giant impact tore free a large
chunk of Earth more than 4 billion years ago. If this "giant impact"
model is correct, the moon would have been completely molten, and lighter
elements such as hydrogen should have bubbled to the surface and escaped into
space. Since hydrogen is a key component of water, a moon formed by a giant
impact should be dry.
The majority
of lunar samples are in fact very dry and missing lighter elements. Yet
hydrogen-rich apatite crystals are found in a whole host of lunar samples and
have presented a paradox for scientists. Somehow, despite the moon's fiery
beginning, some water and other volatiles may have remained, though perhaps not
as much as apatite initially implied.
"We had
40 years of believing in a dry moon, and now we have some evidence that the old
dry model of the moon wasn't perfect," Boyce said. "However, we need
to be cautious and look carefully at each piece of evidence before we decide
that rocks on the moon are as wet as those on Earth."
This study
shows that scientists still have much to learn about the composition and
environment of the early moon.
"We're
knocking out one of the most important pillars of evidence regarding the
conditions of the formation and evolution of the moon," Boyce said.
"Next, we plan to determine how badly apatite has distorted our view of
the moon and how we can best see past it to get at the moon's origin."
Story
Source:
The above
story is based on materials provided by University of California - Los Angeles. The original
article was written by Kim DeRose. Note: Materials may be edited for content
and length.
Journal
Reference:
- J. W. Boyce, S. M. Tomlinson, F. M. McCubbin, J. P. Greenwood, A. H. Treiman. The Lunar Apatite Paradox. Science, 2014; DOI: 10.1126/science.1250398
Cite This
Page:
University of California - Los
Angeles. "Misleading mineral may have resulted in overestimate of water in
moon." ScienceDaily. ScienceDaily, 1 April 2014. <www.sciencedaily.com/releases/2014/04/140401131137.htm>.