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'Like
a giant elevator to the stratosphere:' Newly discovered atmospheric layer may
impact Earth's climate
'Like
a giant elevator to the stratosphere:' Newly discovered atmospheric layer may
impact Earth's climate
Date:
April 4,
2014
Source:
Alfred Wegener Institute, Helmholtz
Centre for Polar and Marine Research
Summary:
An international team of researchers has discovered a
previously unknown atmospheric phenomenon over the tropical West Pacific. Like
in a giant elevator to the stratosphere, many chemical compounds emitted at the
ground pass unfiltered through the so-called 'detergent layer' of the
atmosphere, known as the 'OH shield.' The newly discovered phenomenon over the
South Seas boosts ozone depletion in the polar regions and could have a
significant influence on the future climate of the Earth.
...................................
An international team of researchers headed by Potsdam
scientist Dr. Markus Rex from the Alfred Wegener Institute has discovered a
previously unknown atmospheric phenomenon over the South Seas. Over the
tropical West Pacific there is a natural, invisible hole extending over several
thousand kilometres in a layer that prevents transport of most of the natural
and humanmade substances into the stratosphere by virtue of its chemical
composition. Like in a giant elevator, many chemical compounds emitted at the
ground pass thus unfiltered through this so-called "detergent layer"
of the atmosphere. Scientists call it the "OH shield." The newly
discovered phenomenon over the South Seas boosts ozone depletion in the polar
regions and could have a significant influence on the future climate of Earth
-- also because of rising air pollution in South East Asia.
At first Dr.
Markus Rex suspected a series of flawed measurements. In October 2009 the
atmospheric physicist from the Alfred Wegener Institute, Helmholtz Centre for
Polar and Marine Research (AWI) was on board the German research vessel
"Sonne" to measure trace substances in the atmosphere in the tropical
West Pacific. Tried and tested a thousand times over, the ozone probes he sent
up into the tropical sky with a research balloon every 400 kilometres reported
-- nothing. Or to be more accurate: almost nothing. The ozone concentrations in
his measurements remained nearly constantly below the detection limit of
approx. 10 ppbv in the entire vertical range from the surface of Earth to an altitude
of around 15 kilometres. Normally ozone concentrations in this part of the
atmosphere are three to ten times higher. (One part of ozone per billion by
volume (ppbv) means there is one ozone molecule for every billion air
molecules.)
Although low
values at an altitude of around 15 kilometres were known from earlier
measurements in the peripheral area of the tropical West Pacific, the complete
absence of ozone at all heights was surprising. However, after a short period
of doubt and various tests of the instruments it dawned on the worldwide
recognized ozone specialist that he might be onto a phenomenon yet unknown to
science. A few research years later and after the involvement of other
colleagues came confirmation: Markus Rex and his team on board the
"Sonne" had tracked down a giant natural hole over the tropical South
Seas, situated in a special layer of the lower atmosphere known as the "OH
shield." The research results on the newly discovered OH minimum will be
published soon in the journal Atmospheric Chemistry and Physics, with
the Institute of Environmental Physics of the University of Bremen and other
international research institutions as partners.
"Even
though the sky appears to be an extensively uniform space for most people, it
is composed of chemically and physically very different layers," Markus
Rex explains the complex makeup of the atmosphere. The air layers near the
ground contain hundreds or even thousands of chemical compounds. This is why
winter and spring, mountains and sea, city and forests all have a distinct
smell. The great majority of these substances are broken down into
water-soluble compounds in the lower kilometres of the atmosphere and are
subsequently washed out by rain. Since these processes require the presence of
a certain chemical substance, the so called hydroxyl (=OH) radical, this part
of the atmosphere is called the "OH shield." It acts like a huge
atmospheric washing machine in which OH is the detergent.
The OH
shield is part of the troposphere, as the lower part of the atmosphere is
called. "Only a few, extremely long-lived compounds manage to make their
way through the OH shield," says Rex, "then they also get through the
tropopause and enter the stratosphere." Tropopause refers to the boundary
layer between the troposphere and the next atmospheric layer above it, the
stratosphere. Particularly substances that enter the stratosphere unfold a
global impact. The reason for this is that once they have reached the
stratosphere, their degradation products remain up there for many years and
spread over the entire globe.
Extremely
long-lived chemical compounds find their way to the stratosphere, even where
the OH shield is intact. These include methane, nitrous oxide ("laughing
gas"), halons, methyl bromide and chlorofluorocarbons (CFCs), which are
notorious as "ozone killers" because they play a major role in ozone
depletion in the polar regions.
After many
years of research scientists now understand the complicated process of
stratospheric ozone depletion very well. "Nevertheless measured ozone
depletion rates were often quite a bit larger than theoretically calculated in
our models," Markus Rex points out a long unsolved problem of atmospheric
research. "Through the discovery of the OH hole over the tropical West
Pacific we have now presumably made a contribution to solving this
puzzle." And at the same time discovered a phenomenon that raises a number
of new questions for climate policy. Researchers are now tackling these
questions in a new research project funded by the EU with around 9 million
euros, i.e. "StratoClim," which is coordinated by the Alfred Wegener
Institute. Within this project a new monitoring station will be established in
the tropical Westpacific, together with the Institute of Environmental Physics
at the University of Bremen.
"We
have to realise," reminds the Potsdam atmospheric physicist, "that
chemical compounds which enter the stratosphere always have a global
impact." Thanks to the OH hole that the researchers discovered over the
tropical Pacific, greater amounts of brominated hydrocarbons can reach the
stratosphere than in other parts of the world. Although their ascent takes
place over the tropical West Pacific, these compounds amplify ozone depletion
in the polar regions. Since scientists identified this phenomenon and took it
into account in the modelling of stratospheric ozone depletion, their models
have corresponded excellently with the actually measured data.
However, it
is not only brominated hydrocarbons that enter the stratosphere over the tropical
West Pacific. "You can imagine this region as a giant elevator to the
stratosphere," states Markus Rex using an apt comparison. Other
substances, too, rise here to a yet unknown extent while they are intercepted
to a larger extent in the OH shield elsewhere on the globe. One example is
sulphur dioxide, which has a significant impact on the climate.
Sulphur
particles in the stratosphere reflect sunlight and therefore act
antagonistically to atmospheric greenhouse gases like CO2, which
capture the heat of the sun on Earth. To put it simply, whereas greenhouse
gases in the atmosphere heat the globe, sulphur particles in the stratosphere
have a cooling effect. "South East Asia is developing rapidly in economic
terms," Markus Rex explains a problem given little attention to date.
"Contrary to most industrial nations, however, little has been invested in
filter technology up to now. That is why sulphur dioxide emissions are
increasing substantially in this region at present."
If one takes
into account that sulphur dioxide may also reach the stratosphere via the OH
hole over the tropical West Pacific, it quickly becomes obvious that the
atmospheric elevator over the South Seas not only boosts ozone depletion, but
may influence the climate of the entire Earth. In fact, the aerosol layer in
the stratosphere, which is also composed of sulphur particles, seems to have
become thicker in recent years. Researchers do not know yet whether there is a
connection here.
But wouldn't
it be a stroke of luck if air pollutants from South East Asia were able to
mitigate climate warming? "By no means," Markus Rex vigorously shakes
his head. "The OH hole over the South Seas is above all further evidence
of how complex climate processes are. And we are still a long way off from being
in a position to assess the consequences of increased sulphur input into the
stratosphere. Therefore, we should make every effort to understand the
processes in the atmosphere as best we can and avoid any form of conscious or
unconscious manipulation that would have an unknown outcome."
Background:
Why is there
an OH hole over the West Pacific?
The air in
the tropical West Pacific is extremely clean. Air masses in this area were
transported across the expanse of the huge Pacific with the trade winds and for
a long time no longer had contact with forests or other land ecosystems that
produce innumerable short-lived hydrocarbons and release them into the air.
Under these clean air conditions OH is formed from ozone through chemical
transformation to a great degree. If there is hardly any ozone in the lower
atmosphere (= troposphere), as is the case in the West Pacific, only little OH
can be formed. The result is an OH hole.
Ozone, in
turn, forms in the lower atmosphere only if there are sufficient nitrogen
oxides there. Large amounts of nitrogen oxide compounds are produced in
particular by intensive lightning over land. However, the air masses in the
tropical West Pacific were not exposed to any continental tropical storms for a
very long time during their transport across the giant ocean. And the lightning
activity in storms over the ocean is relatively small. At the same time the
lifetime of atmospheric ozone is short due to the exceptionally warm and moist
conditions in the tropical West Pacific. In this South Sea region the surface
temperatures of the ocean are higher than anywhere else on our planet, which
makes the air not only quite warm, but also quite moist. The ozone is thus
quickly lost, especially directly above the water. And due to the lack of nitrogen
oxide compounds little ozone is subsequently formed. Rapid vertical mixing in
the convection areas that exist everywhere over the warm ocean and in which the
warm air rises takes care of the rest. Finally, there is no more ozone in the
entire column of air in the troposphere. And without ozone (see above) the
formation of OH is suppressed.
What impact
does the OH hole over the West Pacific have?
The OH
molecule is also called the detergent of the atmosphere. Nearly all of the
thousands of different chemical substances produced by people, animals, plants,
fungi, algae or microorganisms on the ground or in the oceans react quickly
with OH and break down in this process. Therefore, virtually none of these
substances rises into the stratosphere. In the area of the OH hole, however, a
larger portion of this varied chemical mix can enter the stratosphere.
And local
emissions may unfold a global impact, especially if they make it to the
stratosphere. There they spread globally and can influence the composition of
the air for many years -- with far-reaching consequences for ozone chemistry,
aerosol formation and climate.
Why wasn't
the OH hole discovered earlier?
The tropical
West Pacific is one of the most remote regions on our planet. That is why
extensive measurements of the air composition have yet to take place in this
area. There is also a considerable gap in the otherwise dense network of global
ozone measurement stations here. Even in the past measurements from the
peripheral sections of the now investigated region showed minimal ozone values
in the area of the upper troposphere, but not the consistently low values that
have now been found across the entire depth of the troposphere. The newly
discovered phenomenon reveals itself in its full scope only through the
measurements that were conducted to such an extensive degree for the first time
and was thus not able to be grasped at all previously.
Story
Source:
The above
story is based on materials provided by Alfred
Wegener Institute, Helmholtz Centre for Polar and Marine Research. Note:
Materials may be edited for content and length.
Cite This
Page:
Alfred Wegener Institute, Helmholtz
Centre for Polar and Marine Research. "'Like a giant elevator to the
stratosphere:' Newly discovered atmospheric layer may impact Earth's
climate." ScienceDaily. ScienceDaily, 4 April 2014.
<www.sciencedaily.com/releases/2014/04/140404092931.htm>.